Best of Luck
Higher Secondary Quarterly Examination- 2012
- 13
Part III − CHEMISTRY
Time Allowed : 3 Hours]
[Maximum Marks : 150
INSTRUCTION: 1. Check the question paper for fairness of printing. If there is any
lack of fairness,
inform the
Hall Supervisor
immediately.
2. Use blue or black ink to
write
and pencil to draw diagrams.
Draw diagrams and write equations wherever necessary.
PART − I
N.B. i) Answer All the questions.
ii) Choose and write the correct answer.
iii) Choose
the correct answer and write the option code & the corresponding answer 30 x
1 = 30
1. The value of Bohr radius for hydrogen
atom
is
a)
0.529 × 10−8cm b) 0.529 × 10−10cm c)
0.529 × 10−6cm d) 0.529 × 10−12cm2
2. Among the following which compound has the strongest hydrogen bond ?
a) HF b) H2O
c) NH3 d) HCN
3. Among the following which has
higher electron affinity value ?
a) Fluorine
b) Chlorine
c) Bromine d) Iodine
4. Effective nuclear
charge (Z*)
can be calculated by using the formula
a) Z*= Z − S b) Z* = Z + S c) Z* = S − Z d) Z = Z* − S
5. The ‘p’ block element which play a vital role in computer is
a) N b) Si c) Br d) S
6. Halogens belong to the
group number
a) 14 b) 15 c) 17 d) 18
7. The oxidation state of iron in
Fe(CO)5 is
a) +2 b) + 3 c) 0 d) + 1
8. The chemical composition of slag formed during the smelting process in the extraction of copper is
a) Cu2O + FeS b) FeSiO3 c) CuFeS2 d) Cu2S + FeO
9. The general electronic
configuration of
actinide is
a) [Rn]5f 0 − 14 6d 0 7s 0
b) [Rn]5f 0 − 14 6d 0 − 2 7s 0
c) [Rn] 5f 0 − 14 6d 0−2 7s 1 d) [Rn]5f 0 − 14 6d 0 − 2 7s 2
10. The maximum oxidation state
exhibited by lanthanide is
a) + 4 b) + 3 c) + 6 d) + 2
11. Example for
molecular crystal
is
a) water b) sodium chloride c)magnesium chloride d) cesium chloride
12. The number of
close neighbours in a
body centred cubic lattice of identical sphere is
a) 6 b) 4 c) 12 d) 8
13. Which of the
following does not result in an increase in
a)
Crystallization of sucrose from solution
b) Rusting of iron
c) Conversion
of ice to water d)
Vaporization of camphor
14. The liquid which deviate from Trouton’s rule is
a) He b) CCl4 c) O2 d) C6H6
15. Change in Gibbs free
energy is given by
a) ΔG = ΔH + TΔS
b) ΔG = ΔH – TΔS c) ΔG = ΔH x TΔS d) None of the above
16. The relationship between KP & KC for the reaction 2H2O (g) + 2Cl2(g) ⇌4HCl(g) + O2(g) is
a) KP < KC b) KP = KC c)KP > KC d) KP = KC /RT
17. State of chemical equilibrium is
a) dynamic b) stationary c) none
of (a) & (b) d) both (a) & (b)
18. The decomposition of nitrogen pentoxide in the presence of CCl4, the order of the reaction is
a) 3 b) 2 c) pseudo first
order
d) 1
19. Arrhenius equation is
a) k = Ae−1/RT b) k = Ae− RT/Ea c) k = Ae−Ea/RT d) k = Ae Ea/ RT
20. Reactions in which the reacting molecules react in more than one way
yielding different
set of products are called
a) consecutive
reactions b) parallel reactions
c) opposing reactions
d) chain reactions
21. The number of secondary alcoholic group in glycerol is
a) 1 b) 2 c) 3 d) 0
22. _______ is used in antiseptic ointments.
a)
phenol b) ethylene
glycol c)
benzyl alcohol d) glycerol
23. IUPAC name of glycerol is
a) propane − 1, 2, 3 – triol b) Ethane − 1, 2 – diol c) 2− propanol
d) Propane − 1, 2 − diol
24. A Compound
that undergoes bromination easily
is
a) Benzoic acid
b) Benzene c) phenol d) toluene
25. Williamson’s synthesis is an example of
a)
nucleophilic addition b) electrophilic addition
c)
electrophilic substitution d) Nucleophilic substitution reaction
26. According to Lewis concept of acids and
bases, ethers are
a)
neutral b) acidic c)
basic d) amphoteric
27. The isomerism between methyl-n-propyl ether and diethyl ether is
a)
functional isomerism b)
position isomerism
c)
metamerism
d) chain isomerism
28. Which of the following does not give iodoform test?
a) acetophenone b) benzophenone
c) CH3 − CHOH d) CH3 − CH − CH2 − CH2 − CH3
| |
CH3 OH
29. The compound
used
in the preparation of the tranquilliser, sulphonal
is
a)
acetone b) acetophenone
c) isopropyl alcohol d) glycol
30. The compound which undergoes
aldol condensation is
a)
CH3CHO b) HCHO c) C6H5CHO d) C6H5COC6H5
PART − II
N.B.
i)
Answer
any fifteen
questions.
ii) Each answer should be in one or two sentences. 15 x 3 = 45
31. Distinguish between a
particle and wave.
32. The ionization energy
of carbon is greater than that of Boron. Why?
33. What is
meant by
inert pair effect?
34. Why HF is not stored in glass bottles?
35. Why d-block elements act as catalyst?
36. Give the
reaction of gold on
aqua
regia.
37. What is the action of heat on copper sulphate crystals?
38. State Bragg’s law.
39. For a chemical reaction the
values of
ΔH and ΔS at 300K
are −10kcal.mol
−1 and 20cal.deg−1mol−1
respectively. What is the value of ΔG of the reaction?
40. Define reaction
quotient.
41. State Le Chatelier’s principle.
42. Define pseudo first order
reaction with example.
43. What is activation energy?
44. Define opposing reaction with
example.
45. What are the conditions for a
compound to be optically active?
46. What is geometrical isomerism?
47. How is dioxane prepared from
ethylene glycol?
48. How is glycerol synthesized from
propylene?
49. Give a test for phenol.
50. Compound (A) reacts with ammonia
to give compound (B) which is used as a urinary antiseptic.
Identify (A) and (B) and give the
structure of compound (B).
51. How is mesitylene prepared ?
PART − III
N.B. Answer any seven questions choosing at least two questions from each
section. 7 x 5 = 35
SECTION − A
52. Explain the formation of N2
molecule by molecular orbital theory.
53. Give the importance of hydrogen
bonding.
54. Explain the extraction of zinc from
its ore.
55. Distinguish between lanthanides
and actinides.
SECTION − B
56. Give the various statements of
second law of thermodynamics.
57. Derive the relationship between
KP and KC for a
general equilibrium reaction.
58. List the characteristics of
order of the reaction.
59. Derive the equation for first
order rate constant.
SECTION − C
60. Give the methods of preparing
anisole.
61. How does diethyl ether react
with the following reagents?
a) O2 / long contact b) HI in excess c) PCl5 d) dil H2SO4
62. Write a brief account on
a) Perkin's reaction b) Knoevenagal reaction.
63. Explain the crossed aldol
condensation mechanism.
PART − IV
N.B. i)
Question No.70 is compulsory
and answer any three from the remaining questions.
ii) Answer four questions in all. 4 x 10 = 40
64. (a) Explain Pauling method to
determine the ionic radii.
(b) Give the uses of silicones.
65. (a) Explain the factors
affecting electron affinity.
(b) Give the anomalous nature of
fluorine.
66. (a) Explain Bragg’s spectrometer
method.
(b) Show that for a first order reaction time required for 99% completion
is twice the time required
for
90% completion of the reaction.
67. (a) Give the characteristics of
glass.
(b) Give the differences between
simple and complex reactions.
68. (a) Describe the conformations
of cyclohexanol. Comment on their stability.
(b) Distinguish between
Enantiomer and Diastereomer.
69. (a) How are primary, secondary and tertiary alcohols distinguished by
Victor Meyer method ?
(b) Explain the following reactions :
i) Riemer
– Tiemann reaction ii) Phthalein
fusion
70. (a)
An organic compound (A) of
molecular formula C2H6O reacts with metallic Na to liberate hydrogen. Compound (A) in the presence of Conc. H2SO4 and at 440 K gives compound
(B) which is an alkene. Compound (B) on treatment
with cold, dilute alkaline KMnO4 gives
compound (C) of
molecular formula
C2H6O2. Identify compounds (A), (B) and (C) and explain the
reactions.
(b)
A chief ore (A) of an element with group number-6 and period number-4in the periodic table is roasted with molten alkali in
the presence of free supply of air gives a water soluble compound
(B). Compound (B)
on acidification gives compound (C). Compound (C) on treatment with KCl
gives
compound (D). Compound (D) is used in the detection of chloride ions in qualitative analysis. Identify A, B, C and D and give the reactions.
(OR)
(c) Compound (A) of M.F. C7H6O which does not reduce Fehling’s solution but reacts with N2H4 and KOH
to give compound (B) of M.F. C7H8. (A) on heating
with NaOH gives compound (C) and (D). Identify
(A), (B), (C), (D) and explain the reactions.
(d) A white lustrous
metal (A) reacts with dil HNO3 to give compound (B)
which is called as Lunar caustic. Compound (B) reacts with KBr to give
compound (C) which is used in photography. Identify A, B, C and explain the reactions.