April 20, 2020

9. Solutions


2 & 3 Marks
1. What is a Solution?
2. What is a Solvent and Solute? Explain with an example.
3. What is Aqueous solution and Non-aqueous solution? Give examples.
4. What is a Gaseous Solution? Give examples.
5. What is a Liquid Solution? Give examples.
6. What is a Solid Solution? Give examples.
7. Mention the Different concentration units.
8. What is meant by Concentration of a solution?
9. Define Molality.
10. Define Molarity.
11. Define Normality.
12. Define Formality.
13. Define Mole fraction (of a component).
14. Define Mass percentage.
15. Define Volume percentage.
16. Define Mass by volume percentage.
17. Define Parts per million (ppm).
18. What is a Standard solution? Or What is a Stock solution?
19. How can you prepare a Standard solution of required concentration?
20. What is a Working standard?
21. How can you prepare a Working standard of required concentration? Or
      How can you prepare solutions of required concentrations by diluting the Stock solution?
22. Give the expression for the calculation of Necessary volumes of the Stock solution and Final volume and explain the terms.
23. What are the Advantages of using Standard solutions?
24. What is the Solubility of a solute?
25. What is a Saturated solution?
26. Define Solubility.
27. You are provided with a solid ‘A’ and three solutions of A dissolved in water - one Saturated, one Unsaturated, and one Super saturated. How would you determine which solution is which?
28. What are the Factors influencing the Solubility (of a Solute in a Solvent)?
29. Explain the effect of Temperature of a Solid solute in Liquid solvent on the Solubility.
30. Explain the effect of Temperature of a Gaseous solute in Liquid solvent on the Solubility.
31. Show with an activity that there is a Decrease in Solubility of gases in solution with Increase in Temperature. Or Show with an activity that the Increase in Temperature Decreases the Dissolution of gaseous molecules in Liquid Solvents.
32. Explain the effect of Pressure on the Solubility.
33. What are the Factors influencing the Solubility of a Gas in a Liquid?
34. Define Henry’s law. Or State Henry’s law.
35. Which properties are related in Henry’s Law?
36. What are the Limitations of Henry’s law?
37. Explain why the aquatic species are more comfortable in cold water during winter season rather than warm water during the summer.
38. What is Evaporation?
39. What is Condensation?
40. What is a Vapour pressure of liquid?
41. What is a Binary solution? Give examples.
42. State Raoult Law.
43. Which properties are related in Raoult Law?
44. What is Relative lowering of vapour pressure?
45. Compare Raoult’s law and Henry’s law.
46. What are Ideal solutions? Give examples.
47. Mention the characteristics of Ideal solutions.
48. What are Non-ideal / Real solutions? Give examples.
49. When will Non-ideal / Real solutions show Positive deviation from Rauolt's Law? Give examples.
50. When will Non-ideal / Real solutions show Negative deviation from Rauolt's Law? Give examples.
51. Mention the characteristics of Non-ideal / Real solutions.
52. What are the factors responsible for deviation from Raoult’s law / ideal behavior?
53. Solute-solvent interactions are responsible for deviation from Raoult’s law / ideal behavior - Explain.
54. Dissociation of solute is responsible for deviation from Raoult’s law / ideal behavior - Explain.
55. Association of solute is responsible for deviation from Raoult’s law / ideal behavior - Explain.
56. Temperature is responsible for deviation from Raoult’s law / ideal behavior - Explain.
57. Pressure is responsible for deviation from Raoult’s law / ideal behavior - Explain.
58. Concentration is responsible for deviation from Raoult’s law / ideal behavior - Explain.
59. What are Colligative properties? What are they?
60. What is a Boiling point?
61. What is Elevation of boiling point?
62. Define Molal boiling point elevation constant. Or Define Ebullioscopic constant.
63. What is a Freezing point?
64. What is Depression of freezing point?
65. Define Molal freezing point depression constant. Or Define Cryoscopic constant.
66. What is Molal depression constant? Does it depend on nature of the solute?
67. Which solution has the lower freezing point? 10 g of Methanol (CH3OH) in 100 g of water (or) 20 g of Ethanol (C2H5OH) in 200 g of water.
68. What is Osmotic pressure?
69. What are the Significances of Osmotic pressure?
70. What are Isotonic solutions? Or Define the term ‘Isotonic solution’.
71. What is meant by van’t Hoff factor?  Or Define Van't Hoff factor.
72. Calculate Degree of dissociation / association related to Van't Hoff factor.

 5 Marks
1. Classify solutions based on the Physical state of the Solute and Solvent. Give examples.
2. Explain the effect of Nature of solute and solvent on the Solubility.
3. Explain Henry’s law.
4. Obtain expression for Total pressure formed when a volatile liquid is dissolved in solvent.
5. Obtain expression for Lowering of vapour pressure when Non-volatile solute is dissolved in solvent.
6. Explain the deviation of Real / Non-ideal solutions from Raoult’s Law.
7. Explain the factors responsible for deviation from Raoult’s law / ideal behavior.
8. How will you determine the molar mass of a Non-volatile solute from relative lowering of vapour pressure?
9. How will you determine the Molar mass of a Non-volatile solute from Elevation of boiling point?
10. How will you determine the Molar mass of a Non-volatile solute from Depression in freezing point?
11. How will you determine the Molar mass of a Non-volatile solute from Osmotic pressure?
12. Explain Reverse osmosis.
13. Write a note on Abnormal molar mass. Or Explain the Abnormal colligative properties.
14. Write a note on Van't Hoff factor.

Problems Molality, Molarity, Normality, Formality, Mole fraction, Mass percentage, Volume percentage, Mass by volume percentage, Parts per million (ppm), diluting the Stock solution, Henry’s law, Molar mass of a Non-volatile solute, Osmotic pressure, van’t-Hoff factor, Moles of solute particles.

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